Two factors must be taken into consideration in explaining
this periodic trend
(1) Increasing nuclear charge
(2) Increasing shell
Along a period (left to right) the the atomic number increases
while the valence electrons remain in the same shell. Thus due
to the increasing nuclear charge (pulling electrons closer to
the nucleus) the radii of the atoms decrease left to right.
Top to bottom along a group the atomic number continues to
increase. However the shell increases from shell 1 to shell 2
etc.. The atomic orbitals for each successive shell get larger
and larger - more than compensating for the increased nuclear
charge. The result is atomic radii increase top to bottom along
a group.
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